Education | Experience | Courses | Research | Publications | Professional Services |
| Awards | Patent | Research Group | Conference Publications |
08/2008 – present: Assistant Professor, Department of Chemistry and Environmental Sciences, Southern Illinois University Edwardsville, Edwardsville, Illinois
08/2005 – 07/2008: National Research Council Postdoctoral Associate, National Exposure Research Laboratory, U. S. EPA, Athens, GA (Research Advisor: Dr. Eric J. Weber)
08/2004 – 08/2005: Postdoctoral Associate, Graduate Field of Environmental Toxicology, Cornell University, Ithaca, New York (Research Advisor: Prof. Ann T. Lemley)
07/2000 – 07/2004: Graduate Research Assistant, School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, Georgia (Research Advisor: Dr. Ching-Hua Huang)
07/1997 – 06/2000: Environmental Engineer, Green Water Treatment Company, Nanjing, Jiangsu, China
09/1994 – 06/1997: Graduate Research Assistant, Dept. of Environmental Science and Engineering, Nanjing University, Nanjing, Jiangsu, China (Research Advisors: Professors. Jing-long Chen and Quanxing Zhang)
Dr. Zhang’s research projects focus on the following areas:
Transformation and fate of emerging contaminants in natural and engineered environments,
Interfacial reactions of contaminants with natural minerals and novel nanomaterials,
Reaction mechanisms and kinetic modeling,
Reduction-oxidation processes in the development of environmental fate models, and
Resources reuse and advanced treatment technology of high concentration industrial wastewaters.
Our primary goal is to contribute to a better understanding of the fate of contaminants in a variety of environments to evaluate the risks associated with these chemicals and their impacts on human health and the environment. We also want to advance the science and application of ‘green’ technology, which focuses on recovery of valuable ingredients from wastewater before they are subject to treatment technologies.
Fate and Transformation of Emerging Contaminants in Reducing Environments
The rapid expansion of the chemical industry has resulted in the potential for release to the environment of approximately 80,000 xenobiotic chemicals resulting in exposure to both humans and ecological receptors. Many of the emerging contaminants have estimated environmental persistence of many years, as is often found with xenobiotics. To provide more accurate environmental fate data for risk analysis, existing environmental fate models need to be updated concerning reductive transformation pathways. The majority of research in the literature is focused on the fate of nitroaromatic, halogenated and azo compounds in model reducing systems; however, little information is available regarding the reduction of compounds containing other functional groups such as sulfoxide, N-nitrosoamine, and quinone functional groups and reductive dealkylation. This poses major uncertainty in trying to incorporate reductive transformation into environmental fate models. For this project, we are studying the reductive transformation of organic contaminants containing all potentially reducible functional groups to gain a systematic understanding of how each functional group reacts and how the reactivity of each functional group is affected by the substituents. The results of this research will significantly enhance the database for environmental fate modeling, as well as provide first-hand information regarding predicting the reductive transformation of contaminants in the environment.
Effects of Nanoparticles on the Redox Transformation of Organic Contaminants
With the increasing number of commercial applications for nanoparticles such as nanosized metal oxides and carbon nanotubes, there is concern about the risk of these materials on human health and the environment. The interaction of these nanoparticles with emerging contaminants must be determined to assess this risk; in particular, how do these nanoparticles affect the fate and transformation of emerging contaminants? Such information would enable toxicologists and environmental scientists to assess the toxicology and the environmental impact of these materials. For this project, we plan to study the effects of nanosized metal oxides on the reduction-oxidation of organic contaminants at metal-oxide interface; and the following questions must be addressed: How does the presence of these materials affect the reaction kinetics and mechanisms of organic contaminants in close contact with them? How will their reactivity differ from their bulk state? The growing number of studies on nanomaterials in the literature will form an important knowledge basis for this research.
Resources Reuse and Advance Treatment of Industrial Wastewater
The demand for advanced wastewater treatment continues to increase because of the growing market for chemical products and higher standards for treated water. For example, in addition to the list of primary drinking water contaminants, EPA announced the draft Drinking Water Contaminant Candidate List 3 (CCL 3) in February 2008 in an effort to expand and strengthen the underlying CCL listing process to be used for future CCLs. For this project, we will study treatment and resources reuse of high concentration organic pollutant-containing wastewaters using advanced oxidation and resin adsorption technologies. Our focus will be on (i) recycling active ingredients from pesticide- or pharmaceutical- wastewaters using a variety of resins and (ii) treating the remaining wastewaters by advanced treatment technologies. These “green” technologies will enable industry to recycle valuable products and/or intermediates before treating the residues as harmful pollutants in an economically efficient manner.
| 1. | Zhang, H. and Weber, E. J. 2008. "Elucidating the Role of Electron Shuttles in Reductive Transformations in Anaerobic Sediments", Environmental Science and Technology. Accepted |
| 2. | Zhang, H., Chen, W.-R. and Huang, C.-H. 2008. “Kinetic Modeling of Oxidation of Antibacterial Agents by Manganese Oxide”, Environmental Science and Technology. 42(15), 5548–5554. |
| 3. | Zhang, H. and Lemley A. T. 2007. “Evaluation of the Performance of Flow-through Anodic Fenton Treatment in Amide Compounds Degradation”, Journal of Agriculture and Food Chemistry, 55(10), 4073-4079. |
| 4. | Hong S., Zhang, H., Duttweiler C. M., and Lemley A. T. 2007. “Degradation of Methyl tertiary-Butyl Ether (MTBE) by Anodic and Classic Fenton Treatment”, Journal of Hazardous Materials, 144, 29-40. |
| 5. | Zhang, H. and Huang C.-H. 2007. “Adsorption and Oxidative Transformation of Fluoroquinolone Antibiotics and Structurally Related Amines in the Presence of Goethite”, Chemosphere, 66, 1502-1512. |
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A. Conference Symposium Organization
B. Technical Journal Reviewer
C. Professional Organization Affiliation
| Graduate Student : | Saru Taujale |
| Undergraduate Students : | Fausto J Murillo Robert S Choi |
Proceeding Papers:
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Extended Abstracts:
| 3. | Zhang, H. and Weber, E. J. “Elucidating the role of electron transfer mediators in reductive transformations in natural sediments”, Preprints of Extended Abstracts presented at the 234st ACS National Meeting, Symposium honoring Dr. Walter Giger, August 19-24, 2007, Boston, MA. |
| 4. | Zhang, H. and Weber, E. J. “Characterizatrion of chemical reductants in natural sediments”, Preprints of Extended Abstracts presented at the 231st ACS National Meeting, American Chemical Society, Division of Environmental Chemistry (2006), 46(1), 833-839. |
| 5. | Zhang, H. and Huang, C.-H. “Reactivity and Transformation of Antibacterial N-Oxides in the Presence of Manganese Oxide”, Preprints of Extended Abstracts presented at the ACS National Meeting, American Chemical Society, Division of Environmental Chemistry (2004), 44(2), 929-934. |
| 6. | Huang, C.-H. and Zhang, H. "Oxidation of fluoroquinolone antibacterials and structurally related amines with manganese oxide ", Preprints of Extended Abstracts presented at the ACS National Meeting, American Chemical Society, Division of Environmental Chemistry (2003), 43(2), 1257-1260. |
| 7. | Zhang, H. and Huang, C.-H. "Oxidation of Triclosan by Manganese Oxides", Extended Abstract at the American Chemical Society Meeting, Symposium of the Science and Policy of Topical Antimicrobial Agents, April 7-11, 2002, Orlando, FL. |
Conference Presentations (Without Proceedings):
| 8. | Zhang, H. and Weber, E. J. “Identifying Indicators of Reactivity for Chemical Reductants in anoxic and anaerobic sediments”, SETAC North America 28th Annual Meeting, November 11 – 15, 2007. Milwaukee, WI. |
| 9. | Zhang, H. and Lemley A. T. “Kinetic model and optimization of DEET degradation by flow-though anodic Fenton treatment (FAFT)”, the 230st ACS National Meeting, American Chemical Society, Division of Agrochemicals, August 28 - September 1, 2005. Washington, DC. |
| 10. | Huang, C.-H. and Zhang, H. Co-author of an Invited Speech, “Interfacial Transformation of Antibacterial Agents with Metal Oxides”, Gordon Research Conference, Environmental Sciences: Water, June 27 - July 2, 2004. Plymouth, NH. |
| 11. | Zhang, H. and Huang, C.-H. “Oxidation of Fluoroquinolone Antibacterials and Structurally Related Amines with Manganese Oxide”, “Colloids and Interface in the Environment”, 77th ACS Colloid & Surface Science Symposium, June 15-18, 2003. Atlanta, GA. |
| 12. | Zhang, H. and Weber, E. J. “Characterizatrion of Chemical Reductants in Natural Sediments”, Gordon Research Conference Environmental Science: Water, June 25-30, 2006, Plymouth, NY. |
| 13. | Zhang, H. and Weber, E. J. “Elucidating the Role of Electron Transfer Mediators in Reductive Transformations in Reducing Sediments”, Gordon Research Conference Environmental Science: Water, June 25-30, 2006, Plymouth, NY. |
| 14. | Chen, W.-R., Zhang, H., and Huang, C.-H. “Kinetic Models for the MnO2-Mediated Oxidation of Antibacterial Agents and Mechanistic Insight”, Gordon Research Conference Environmental Science: Water, June 25-30, 2006, Plymouth, NY. |
| 15. | Zhang, H. and Huang, C.-H. “Adsorption and oxidative transformation of triclosan with goethite and soils”, Gordon Research Conference Environmental Science: Water, June 26 – July 2, 2004, Plymouth, NH. |
| 16. | Zhang, H. and Huang, C.-H. “Oxidative Transformation of Antibacterial Agents with Manganese Oxides”, Gordon Research Conference Chemical Reactivity and Bioavailability in Environmental Systems: Assessing the State of the Science for Metals and Organic Chemicals, June 23-28, 2002, Plymouth, NH. |
| 17. | Zhang, H. and Huang, C.-H. “Oxidative Transformation of Antibacterial Agents by Manganese (Hydr)oxides”, Quadrangle Conference, February 9 - 11, 2002, Chapel Hill, NC. |